Belokon's Ni(II) complex as a chiral masked glycine for the diastereoselective synthesis of 2-substituted 1-aminocyclopropane carboxylic acids

Autor:	Sylvain Collet, Lisenn Euzenat, Patrick Bauchat, Daniel Danion, Bertrand Carboni, Abdelmadjid Debache, Alain Hercouet
Rok vydání:	2001
Předmět:	Inorganic Chemistry chemistry.chemical_compound Schiff base Chemistry Stereochemistry Organic Chemistry Glycine Benzophenone Physical and Theoretical Chemistry Sulfate Catalysis
Zdroj:	Tetrahedron: Asymmetry. 12:761-764
ISSN:	0957-4166
DOI:	10.1016/s0957-4166(01)00106-9
Popis:	(1S,2R)- and (1R,2S)-Allonorcoronamic acids have been efficiently synthesised from the cyclic sulfate of 1,2-propanediol and Belokon's complex (a complex of Ni(II) with glycine-(S)-2-[N′-(N-benzylprolyl)amino]benzophenone Schiff base ligands). The stereochemical outcome of the reaction was totally controlled by the sulfate partner.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7368e7edec463629ab7db168a4df942d https://doi.org/10.1016/s0957-4166(01)00106-9 Zobrazit plný text záznamu Full Text from ScienceDirect