SYNTHESIS AND CHARACTERIZATION OF THE NOVEL BRIDGED LIGAND 5,8-DIMETHYL-1,5,8,12-TETRAAZABICYCLO[10.3.2]HEPTADECANE AND ITS COMPLEXES WITH IRON(II) AND MANAGANESE(II) IONS
Autor: | Simon R. Collinson, Daryle H. Busch, Timothy J. Hubin, Nathaniel W. Alcock |
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Rok vydání: | 2001 |
Předmět: | |
Zdroj: | Journal of Coordination Chemistry. 52:317-331 |
ISSN: | 1029-0389 0095-8972 |
Popis: | The bridged tetradentate ligand 5,8-dimethyl-1,5,8,12-tetraazabicyclo[10.3.2]heptadecane (L 1) has been prepared, and its complexes with manganese(II) and iron(II) synthesized and characterized. The crystal structure of MnL 1(NCS)2 has been determined; the Mn is octahedral with cis-NCS ligands, and the asymmetric unit contains two independent molecules differing slightly in the Mn—N—C angles. The oxidation of the complexes by hydrogen peroxide is also discussed. |
Databáze: | OpenAIRE |
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