SYNTHESIS AND CHARACTERIZATION OF THE NOVEL BRIDGED LIGAND 5,8-DIMETHYL-1,5,8,12-TETRAAZABICYCLO[10.3.2]HEPTADECANE AND ITS COMPLEXES WITH IRON(II) AND MANAGANESE(II) IONS

Autor:	Simon R. Collinson, Daryle H. Busch, Timothy J. Hubin, Nathaniel W. Alcock
Rok vydání:	2001
Předmět:	Heptadecane Ligand Inorganic chemistry chemistry.chemical_element Manganese Crystal structure Ion chemistry.chemical_compound chemistry Octahedron Polymer chemistry Materials Chemistry Molecule Physical and Theoretical Chemistry Hydrogen peroxide
Zdroj:	Journal of Coordination Chemistry. 52:317-331
ISSN:	1029-0389 0095-8972
Popis:	The bridged tetradentate ligand 5,8-dimethyl-1,5,8,12-tetraazabicyclo[10.3.2]heptadecane (L 1) has been prepared, and its complexes with manganese(II) and iron(II) synthesized and characterized. The crystal structure of MnL 1(NCS)2 has been determined; the Mn is octahedral with cis-NCS ligands, and the asymmetric unit contains two independent molecules differing slightly in the Mn—N—C angles. The oxidation of the complexes by hydrogen peroxide is also discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::73578cd163b44d9d985b2beaf6f10489 https://doi.org/10.1080/00958970108028181 Zobrazit plný text záznamu