Catalytic phosphorylation of polyfluoroalkanols 6. Formation of ?-polyfluoroalkylbenzyl ethers during catalytic phosphorylation of ?-polyfluoroalkylbenzyl alcohols

Autor:	E. P. Lur'e, L. S. Zakharov, L. L. Morozov, M. I. Kabachnik, E. I. Goryunov, V. A. Svoren, T. M. Shcherbina
Rok vydání:	1978
Předmět:	Alcohol Ether General Chemistry Alkylation Chloride Acceptor Medicinal chemistry Catalysis chemistry.chemical_compound chemistry medicine Phosphorylation Organic chemistry Hydrogen chloride medicine.drug
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 27:1843-1847
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00929235
Popis:	1. The formation of α-polyfluoroalkylbenzyl ethers during the catalytic phosphorylation of α-polyfluoroalkylbenzyl alcohols is due to alkylation of these alcohols by α-polyfluoroalkylbenzyl dichlorophosphates formed as intermediates in the course of the reaction. 2. α-Polyfluoroalkylbenzyl dichlorophosphates containing a p-methyl group in the aromatic nucleus can be used as phosphorylating agents only in the presence of a hydrogen chloride acceptor at low temperatures.
Databáze:	OpenAIRE
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