Catalytic hydrochlorination of acetylene on mechanochemically-activated K2PdCl4

Autor:	S. A. Mitchenko, I. V. Zhikharev, T. V. Krasnyakova
Rok vydání:	2008
Předmět:	inorganic chemicals chemistry.chemical_classification Double bond Hydrogen chemistry.chemical_element General Chemistry Photochemistry Triple bond Catalysis Hydrogen halide chemistry.chemical_compound chemistry Acetylene Halogen Isopropyl chloride
Zdroj:	Theoretical and Experimental Chemistry. 44:316-319
ISSN:	1573-935X 0040-5760
Popis:	We report the catalysis of the hydrochlorination of acetylene on the surface of dry K2PdCl4 subjected to prior mechanical activation in an atmosphere of acetylene or propylene. The stereochemistry of the reaction corresponds to trans addition of the halogen and hydrogen atoms to the C-C triple bond. The hydrogen halide is the source of the halogen atom in the reaction product. The mechanical activation of K2PdCl4, in contrast to the case of K2PtCl4, is also capable of activating the C-C double bond: propylene is hydrochlorinated under similar conditions to isopropyl chloride.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::734c76d6c4160091072a081f715524eb https://doi.org/10.1007/s11237-008-9039-4 Zobrazit plný text záznamu Plný text ve formátu PDF