| Autor: |
Ken-ichi Machida, Eiji Yamamoto, Jian-Zhuang Jiang, Gin-ya Adachi |
| Rok vydání: |
2010 |
| Předmět: |
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| Zdroj: |
Chinese Journal of Chemistry. 12:193-198 |
| ISSN: |
1001-604X |
| DOI: |
10.1002/cjoc.19940120301 |
| Popis: |
The electronic behavior of sandwich-type rare earth octaethylporphyrinates Ln(oep)2 and Ln2(oep)3 (Ln=Ce, Pr and Eu) was characterized by measurements of the UV-vis or near infrared spectra and D.C. conductivity. However, the conductivity values measured at room temperature were distributed in an order of 10−7 to 10−8 S·cm−1 even after the partial oxidation of complex with the complexes with iodine and no remarkable change was observed among the complexes such as LnIV(Por2-)2 (Ln=Ce) and LnIV(Por2-)(Por.−) (Ln=Ce) or Ln2III(Por2-)3 and Ln2III(Por2-)2(Por.−). |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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