Facile Synthesis and Crystal Structure of [(PhSO2 N)2 WVI Cl2 (CH3CN)2] - the Oxidative Imination of W(CO)6 by N,N-Dichlorophenylsulphonamide
| Autor: | Herbert W. Roesky, T. Schroeder, Peter G. Jones, Jürgen Schimkowiak, George M. Sheldrick, Mathias Noltemeyer, Jörg Sundermeyer |
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| Rok vydání: | 1985 |
| Předmět: | |
| Zdroj: | Zeitschrift für Naturforschung B. 40:736-739 |
| ISSN: | 1865-7117 0932-0776 |
| Popis: | The reaction of N,N-dichlorophenylsulphonamide with tungsten hexacarbonyl in refluxing CCl4 leads in good yield to the yellow polymeric complex [(PhSO2N)2WCl2]x, which may be converted to the octahedral nitrene complex [(PhSO2N)2WCl2(CH3CN)2] by recrystallisation from acetonitrile. Crystals of the acetonitrile complex are triclinic, space group P 1̅, a = 820.7(2), b = 1128.8(3), c = 1286.9(3) pm, α = 89.25(3), β = 89.54(3). γ = 72.67(2)°, Z = 2, R = 0.027 for 2527 unique observed reflections. |
| Databáze: | OpenAIRE |
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