Metal-free-mediated synthesis of fulleropyrrolines by the reaction of [60]fullerene with β-substituted ethylamines

Autor:	Yongshun Huang, Jun-Jun Xiang, Cheng Huang, Ji-Long Shi, Li Liu, Fa-Bao Li, Hui-Juan Wang, Khalid A. Alamry, Chao-Yang Liu, Abdullah M. Asiri
Rok vydání:	2017
Předmět:	chemistry.chemical_classification Fullerene 010405 organic chemistry Alkene Ethylamines General Chemistry 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences Metal free chemistry Yield (chemistry) Materials Chemistry Organic chemistry
Zdroj:	New Journal of Chemistry. 41:8725-8728
ISSN:	1369-9261 1144-0546
DOI:	10.1039/c7nj01101f
Popis:	The reaction of [60]fullerene with β-substituted ethylamines under air conditions afforded unexpected fulleropyrrolines with trisubstituted alkene functional groups in moderate yields. The conversion of β-substituted ethylamines to their corresponding aldehydes played a crucial role in the successful synthesis of fulleropyrrolines. Promoted by p-toluenesulfonic acid, the obtained fulleropyrroline could (1) be converted back to [60]fullerene in nearly quantitative yield and (2) further react with 1,3-propanediol to generate fullerene-fused dioxepane.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::733c453c969f89f7a6ff7007dba221b1 https://doi.org/10.1039/c7nj01101f Zobrazit plný text záznamu