Investigations on organo-tin compounds. XIII

Autor:	G. J. M. Der Van Kerk, J. G. Noltes
Rok vydání:	2007
Předmět:	chemistry.chemical_classification Aryl Substituent chemistry.chemical_element Halide equipment and supplies Cleavage (embryo) Medicinal chemistry chemistry.chemical_compound chemistry Group (periodic table) Organic chemistry Tin Bond cleavage Alkyl
Zdroj:	Journal of Applied Chemistry. 9:179-185
ISSN:	1934-998X 0021-8871
DOI:	10.1002/jctb.5010090309
Popis:	Whereas in α-substituted organo-tin nitriles and esters the functionally substituted group is easily removed from the tin atom, it appears that groups in which the substituent occupies a β-position or beyond with respect to the tin atom are very resistant to tin-carbon bond cleavage. With compounds containing groups of the latter type, the reactions studied result in rapid cleavage of unsubstituted aryl or alkyl groups. Various organo-tin halides containing alkyl groups substituted in the β-position or beyond are described.
Databáze:	OpenAIRE
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