Detection of hydrogen peroxide and glucose by using Tb 2 (MoO 4 ) 3 nanoplates as peroxidase mimics
| Autor: | Morteza Hosseini, Mehdi Rahimi-Nasrabadi, Amir Homayoun Keihan, Farhang Mizani, Mohammad Reza Ganjali |
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| Rok vydání: | 2017 |
| Předmět: |
chemistry.chemical_classification
Detection limit Oxidase test Blue dye biology Inorganic chemistry 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Atomic and Molecular Physics and Optics 0104 chemical sciences Analytical Chemistry Catalysis Absorbance chemistry.chemical_compound Enzyme chemistry biology.protein 0210 nano-technology Hydrogen peroxide Instrumentation Spectroscopy Nuclear chemistry Peroxidase |
| Zdroj: | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 186:82-88 |
| ISSN: | 1386-1425 |
| DOI: | 10.1016/j.saa.2017.06.006 |
| Popis: | Tb2(MoO4)3 nanostructures are demonstrated for the first time to have an intrinsic peroxidase-like activity. Tb2(MoO4)3 nanoplates could efficiently catalyse the oxidation of 3,3′,5,5′-tetramethylbenzidine (TMB) to generate a blue dye (with an absorbance maximum at 652 nm) in the presence of H2O2. Based on the highly efficient catalytic of Tb2(MoO4)3 nanoplates, a novel system for optical determination of H2O2 and glucose was successfully established under optimized conditions. The assay had 0.0.08 μM and 0.1 μM detection limit for H2O2 and glucose, respectively. In our opinion, this enzyme mimetic has a potential to use in other oxidase based assays. |
| Databáze: | OpenAIRE |
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