Comparative FTIR study of the cobalt and iron porphyrin reactions with CO. Does cobalt porphyrin form a bis-carbonyl complex in the Ar matrix?
| Autor: | H.V. Adonts, T.S. Kurtikyan, G.G. Martirosyan, Gohar Sh. Hovhannisyan |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
010405 organic chemistry
chemistry.chemical_element 010402 general chemistry 01 natural sciences Porphyrin 0104 chemical sciences Adduct Inorganic Chemistry Matrix (chemical analysis) chemistry.chemical_compound chemistry Polymer chemistry Materials Chemistry Physical and Theoretical Chemistry Fourier transform infrared spectroscopy Cobalt Carbon monoxide |
| Zdroj: | Inorganica Chimica Acta. 495:119011 |
| ISSN: | 0020-1693 |
| DOI: | 10.1016/j.ica.2019.119011 |
| Popis: | The adducts of Co(II)(TPP) and Fe(II)TPP (TPP is meso-tetraphenyl-porphyrinato dianion) with carbon monoxide in Ar matrix at 10 K have been studied by FTIR spectroscopy using CO, C18O and their equimolar mixture. It is shown that both metals may form mono-carbonyl adducts with CO, however formation of bis-carbonyl adduct was confirmed only for iron porphyrin. These results refute an earlier assumption regarding existence of Co(TPP)(CO)2 in Ar matrix. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect