Large changes in hydricity as a function of charge and not metal in (PNP)M–H (de)hydrogenation catalysts that undergo metal–ligand cooperativity

Autor:	Kevin Schlenker, Lillee K. Casselman, Ryan T. VanderLinden, Caroline T. Saouma
Rok vydání:	2023
Předmět:	Catalysis
Zdroj:	Catalysis Science & Technology. 13:1358-1368
ISSN:	2044-4761 2044-4753
Popis:	Ligand pKa and metal hydricity scale with one another in (de)hydrogenation catalysts that undergo metal–ligand cooperativity, irrespective of metal or ligand identity. Anionic hydrides are significantly more hydridic than their neutral counterparts.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::72cb4cd32e37623e489323af9e5f75c2 https://doi.org/10.1039/d2cy01349e Zobrazit plný text záznamu