ChemInform Abstract: Photooxygenation of 1,ω-Bis(diarylethenyl)alkanes via Photoinduced Electron Transfer: Formation of Bicyclic Peroxides

Autor:	Toshiyuki Tamai, Yoshio Otsuji, Kazuhiko Mizuno, Isao Hashida
Rok vydání:	2010
Předmět:	chemistry.chemical_compound Bicyclic molecule Chemistry Intramolecular force Photooxygenation General Medicine Acetonitrile Alkadienes Medicinal chemistry Photoinduced electron transfer
Zdroj:	ChemInform. 24
ISSN:	0931-7597
Popis:	The 9,10-dicyanoanthracene (DCA)-sensitized photooxygenation of Ar 2 C=CH(CH 2 ) n CH=CAr 2 in acetonitrile was studied. When Ar = 4-CH 3 OC 6 H 4 , n = 3 and 4, bicyclic peroxides were obtained via 1,4-radical cations that are generated by intramolecular interaction between two ethenyl moieties of the alkadienes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::72b121ecef7f15b0757c4c13634eb2d8 https://doi.org/10.1002/chin.199349099 Zobrazit plný text záznamu Plný text