Dimethyl sulfoxide phase carbon-hydrogen bond dissociation energies for phenalene and benzanthrene

Autor:	G. Jirka, G. Winter, D. Selmarten, R. Gostowski, Mark J. Bausch
Rok vydání:	1990
Předmět:	chemistry.chemical_compound Phenalene chemistry Dimethyl sulfoxide Organic Chemistry Carbon–hydrogen bond activation Fluorene Photochemistry Bond-dissociation energy Redox Dissociation (chemistry) Homolysis
Zdroj:	The Journal of Organic Chemistry. 55:5805-5806
ISSN:	1520-6904 0022-3263
DOI:	10.1021/jo00310a002
Popis:	Comparisons of fluorene, phenalene, and benzathrene sp 3 C-H homolytic bond dissociation energy data, data collected with the aid of a cycle that utilizes acid-base and redox data collected in dimethyl sulfoxide solution, indicate that the sp 3 C-H bonds in phenalene and benzanthrene are about 18 and 16 kcal/mol weaker (in a homolytic sense) than the sp 3 C-H bond in fluorene
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::72aa56e36ebf644ea93226ced0e3b8b3 https://doi.org/10.1021/jo00310a002 Zobrazit plný text záznamu