Radical-mediated imidoylation of telluroglycosides. Insertion of isonitriles into the glycosidic carbontellurium bond

Autor:	Jun-ichi Yoshida, Hiroshi Miyazoe, Shigeru Yamago, Ryuta Goto
Rok vydání:	1999
Předmět:	chemistry.chemical_classification Chemistry Stereochemistry Radical Organic Chemistry Drug Discovery Atom (order theory) Glycosidic bond Biochemistry Medicinal chemistry
Zdroj:	Tetrahedron Letters. 40:2347-2350
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(99)00183-5
Popis:	Telluroglycosides react with isonitriles under photo-thermal conditions to give 1-telluroimidoylglycosides. The reaction proceeds by atom transfer radical reaction to form an imidic CTe bond, which can be substituted to a CC bond and CO bond under oxidative conditions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::72a6e441944e38682f633831b49c45ba https://doi.org/10.1016/s0040-4039(99)00183-5 Zobrazit plný text záznamu Full Text from ScienceDirect