On the polymerization mechanism of 10-vinylphenothiazine in the presence of tetrahalobenzoquinones in benzene

Autor:	G. G. Skvortsova, A. G. Gorshkov, M. F. Larin, V. K. Turchaninov
Rok vydání:	1983
Předmět:	Chain-growth polymerization Polymerization Bulk polymerization Chemistry Polymer chemistry General Engineering Precipitation polymerization Cationic polymerization Chain transfer Solution polymerization Photochemistry Ionic polymerization
Zdroj:	Polymer Science U.S.S.R.. 25:2203-2212
ISSN:	0032-3950
DOI:	10.1016/0032-3950(83)90417-3
Popis:	The polymerization of 10-vinylphenothiazine in the presence of tetrahalobenzoquinones is shown to be an autocatalytic process. The polymerization is catalyzed by hydrogen halide formed as a result of interaction between monomer and initiator. The propagation rate constants for reactions of 10-vinylphenothiazine with p-bromanil and p-chloranil have been determined.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::727b4ae88e148d4cd19534faa210338e https://doi.org/10.1016/0032-3950(83)90417-3 Zobrazit plný text záznamu