Complexing of zinc and eosin porphyrins with viologens in aqueous solutions

Autor:	N. K. Khannanov, V.E. Maier, Vladimir A. Kuzmin, Peter P. Levin, V. Ya. Shafirovich
Rok vydání:	1989
Předmět:	chemistry.chemical_compound Aqueous solution chemistry Eosin Ionic strength Inorganic chemistry Ionic bonding chemistry.chemical_element General Chemistry Zinc Porphyrin Electrostatic interaction
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 38:231-235
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00953602
Popis:	1. The complexing constants of eosin (ZD=−2) and zinc porphyrins (ZD=+4, −4) with charged viologens (ZA=0 to +4) with different ionic strengths were determined. 2. It was shown that ΔG of complexing can be considered the additive sum of the ΔG of a donor-acceptor π interaction which is constant in the dye-viologens series and the ΔG of the electrostatic interaction which changes as a function of the charges of the reactants.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::72564af23df8a8ae3dc07955b8ec3bde https://doi.org/10.1007/bf00953602 Zobrazit plný text záznamu Full text from SpringerLink