Solvent free oxidative coupling polymerization of 3-hexylthiophene (3HT) in the presence of FeCl3 particles
| Autor: | Kazutoshi Yokomachi, Ryuichi Sugimoto, Yuji Higaki, Kevin L. White, Atsushi Takahara, Kazuhiko Saigo, Yuko Konishi, Makoto Kido, Tomoyuki Ohishi, Maiko Nishibori, Yusuke Nagae, Tomoyasu Hirai, Kazutaka Kamitani, Tomoki Uchiyama, Ken Kojio |
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| Rok vydání: | 2016 |
| Předmět: |
Solvent free
Chemistry General Chemical Engineering Side reaction 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Photochemistry 01 natural sciences 0104 chemical sciences Polymerization Molecule Oxidative coupling of methane 0210 nano-technology |
| Zdroj: | RSC Advances. 6:111993-111996 |
| ISSN: | 2046-2069 |
| DOI: | 10.1039/c6ra23178k |
| Popis: | A solvent free oxidative coupling reaction of 3-hexylthiophene (3HT) within a nanocavity is reported. It is found that 3HT can be encapsulated in nanocavities larger than 1 nm, which corresponds to the size of the molecule. In this case, the side reaction at the 4-position in 3HT is regulated. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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