Influence of mechanochemical activation on the rheological, fresh and mechanical properties of one-part geopolymer grout

Autor: Mukhtar ABED, Israa Sabbar, Dr. Hanifi Canakci
Rok vydání: 2023
Předmět:
Zdroj: Advances in Cement Research. 35:96-110
ISSN: 1751-7605
0951-7197
DOI: 10.1680/jadcr.21.00205
Popis: One-part geopolymer (OPG) grout offers advantages over two-part geopolymer grout in the handling and storage of feedstocks, mainly because of the large quantities of caustic solutions that must be handled for producing two-part geopolymer. However, OPG often suffers from a low degree of reaction, a high number of crystalline by-products and, as a result, low strength. Here, one-part geopolymer was assisted by mechanochemical activation (MC-OPG) to produce grout. The precursor materials (slag and fly ash) and sodium silicate were mechanochemically activated utilising co-grinding to produce a geopolymeric precursor, after which water is the only additive required to initiate the geopolymerisation reaction. The effects of slag/fly ash ratios on grout mixtures were also investigated. A series of tests was examined, including rheological characteristics, setting time, bleeding, unconfined compressive strength (UCS), ultrasonic pulse velocity, scanning electron microscopy and X-ray diffraction. The results showed that the mechanochemical activation technique increased the rheological characteristics and reduced the fresh properties (setting time and bleeding) of geopolymer grout compared to the one-part geopolymer. Considering mechanical properties, the UCS of MC-OPG grout was higher (41–73%) than that of OPG grout. Furthermore, slag content significantly affected the rheological, fresh and mechanical properties of all the geopolymer grouts regardless of the activation method.
Databáze: OpenAIRE