Decarboxylation of a Wide Range of Amino Acids with Electrogenerated Hypobromite

Autor:	Laurens Claes, Dirk De Vos, Roman Matthessen, Jan Fransaer, Koen Binnemans
Rok vydání:	2014
Předmět:	chemistry.chemical_classification Decarboxylation Chemistry Organic Chemistry Lysine Electrochemistry Redox Amino acid chemistry.chemical_compound Bromide Organic chemistry Physical and Theoretical Chemistry Selectivity Hypobromite
Zdroj:	European Journal of Organic Chemistry. 2014:6649-6652
ISSN:	1434-193X
DOI:	10.1002/ejoc.201403112
Popis:	Bromide-assisted electrochemical decarboxylation efficiently produces valuable nitriles in high yields from a wide range of naturally occurring amino acids in a single step. Bromide salts are used as both redox mediators and supporting electrolytes in a simple one-compartment setup. As demonstrated for lysine, the selectivity of the decarboxylation can be tuned towards nitriles, amines or amides.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::721e4232861929f0e03819d0619e7974 https://doi.org/10.1002/ejoc.201403112 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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