Crystal structure, thermal decomposition, photoluminescence and magnetic studies of a new two dimensional metal–organic framework constructed from infinite chains of edge-sharing CeO6(H2O)2(NO3) polyhedron with bullet shaped channels

Autor:	S. Suma, M. Sajimol Augustine, Seik Weng Ng, M.R. Sudarsanakumar, Sunalya M. Roy, V.S. Dhanya
Rok vydání:	2013
Předmět:	Photoluminescence Materials science Thermal decomposition Crystal structure Edge (geometry) Magnetic susceptibility Inorganic Chemistry Crystallography Polyhedron chemistry.chemical_compound chemistry Materials Chemistry Metal-organic framework Carboxylate Physical and Theoretical Chemistry
Zdroj:	Inorganic Chemistry Communications. 35:140-143
ISSN:	1387-7003
Popis:	A new cerium–adipate metal–organic framework [Ce(C6H8O4)(H2O)2(NO3)] was grown by simple gel diffusion technique at room temperature. The compound possesses a two dimensional network structure constructed from edge sharing CeO6(H2O)2(NO3) polyhedron. The adjacent polyhedrons are connected by the carboxylate ligand forming the 2D framework with bullet shaped channels running parallel to c axis. Thermal decomposition of the compound takes place in four steps and CeO2 is obtained as the final product. UV–visible spectra, solid state photoluminescence, and magnetic susceptibility measurements were also carried out at room temperature.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::721af81cbe50005c434caa640574b30c https://doi.org/10.1016/j.inoche.2013.06.003 Zobrazit plný text záznamu Full Text from ScienceDirect