Electron yields and the early stages of radiolysis in aqueous systems

Autor:	F. S. Dainton, G. V. Buxton, F. C. R. Cattell
Rok vydání:	1971
Předmět:	Range (particle radiation) Aqueous solution Chemistry Yield (chemistry) Radiolysis Inorganic chemistry Analytical chemistry Electron Solvated electron Ion Pulse (physics)
Zdroj:	Journal of the Chemical Society D: Chemical Communications. :23b
ISSN:	0577-6171
DOI:	10.1039/c2971000023b
Popis:	Pulse radiolysis of 10 M OH– solution between 300 and 77 K shows (i) that the maximum yield of solvated electrons is 5, 30% of which do not escape from the spurs; (ii) that this medium is rigid below 135 K, and (iii) that diffusion-controlled reactions in this medium obey the equation ln k= ln A–E/R(T– 135), values of A lying in the range 1011 to 1012M–1S–1 and E from 6·4 to 7·4 kJ mole–1.
Databáze:	OpenAIRE
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