Synthesis of vanadium, niobium, and tantalum silylimido complexes and reactivity of their nitrogen-silicon bonds

Autor:	Beth M. Schomber, Carolyn M. Jones, Carolyn J. Church, Megan E. Lerchen, Nancy M. Doherty
Rok vydání:	1990
Předmět:	Silicon Stereochemistry Tantalum Niobium chemistry.chemical_element Vanadium Medicinal chemistry Nitrogen Adduct Inorganic Chemistry chemistry.chemical_compound chemistry Pyridine Reactivity (chemistry) Physical and Theoretical Chemistry
Zdroj:	Inorganic Chemistry. 29:1679-1682
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic00334a018
Popis:	A series of group V transition-metal (trimethylsily)imido compounds has been synthesized in which the NSiMe 3 groups derive from hexamethyldisilazane. Reaction of MCl 5 with 2 equiv of NH(SiMe 3 ) 2 produces [M(NSiMe 3 )Cl 3 (NH 2 SiMe 3 )] 2 (M=Nb, Ta). Pyridine and substituted pyridine adducts, M(NSiMe 3 )Cl 3 L 2 (M=Nb, L=py, 4-Mepy, or 1/2 4,4'-Me 2 bpy; M=Ta, L=py), are prepared
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::71fa835cec78c82b741cc0bce4403be1 https://doi.org/10.1021/ic00334a018 Zobrazit plný text záznamu