Reactions of dichloromethane with chalcogens and dimethyl chalcogenides in the hydrazine hydrate-alkali system

Autor:	Lyudmila V. Klyba, V. A. Grabel’nykh, N. A. Korchevin, E. N. Sukhomazova, V. Yu. Vshivtsev, Ekaterina P. Levanova, E. R. Zhanchipova, A. I. Albanov, N. V. Russavskaya
Rok vydání:	2008
Předmět:	Inorganic chemistry Hydrazine chemistry.chemical_element General Chemistry Alkali metal chemistry.chemical_compound Chalcogen chemistry Polymer chemistry Reactivity (chemistry) Dimethyl disulfide Tellurium Hydrate Dichloromethane
Zdroj:	Russian Journal of General Chemistry. 78:1734-1741
ISSN:	1608-3350 1070-3632
DOI:	10.1134/s1070363208090156
Popis:	Methods of synthesis of compounds MeY(CH2Y)nMe (Y=S, Se, Te; n = 1–3) containing several identical or different chalcogen atoms are suggested. The methods are based on the reactions of dichloromethane with elemental chalcogens (Y2−) and dimethyl dichalcogenides (MeY−) activated in the system hydrazine hydrate-alkali. The effect of the chalcogen on the reactivity toward dichloromethane is qualitatively assessed. With elemental tellurium in the system hydrazine hydrate-alkali, reduction of one chlorine atom in dichloromethane and formation of methyltellanyl derivatives are observed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::71f771b7ca4e5c87af1f95e051824761 https://doi.org/10.1134/s1070363208090156 Zobrazit plný text záznamu Plný text ve formátu PDF