Highly selective hydroformylation of internal and terminal olefins to terminal aldehydes using a rhodium-BIPHEPHOS-catalyst system

Autor:	Udo Kragl, Eckhard Paetzold, Christian Vogl, Christine Fischer
Rok vydání:	2005
Předmět:	chemistry.chemical_classification Olefin fiber Alkene Process Chemistry and Technology chemistry.chemical_element Substrate (chemistry) Homogeneous catalysis Aldehyde Catalysis Rhodium chemistry Organic chemistry Physical and Theoretical Chemistry Hydroformylation
Zdroj:	Journal of Molecular Catalysis A: Chemical. 232:41-44
ISSN:	1381-1169
Popis:	In this paper, we describe the hydroformylation of terminal and internal olefins to terminal aldehydes using a catalyst system of rhodium and BIPHEPHOS. According to industrial processes, the catalyst concentration lies in a range from 0.01 to 0.001 mol%. The conversions are, depending of the substrate, up to 99% and yields up to 86% of the aldehydes can be found. The ratio of linear to branched products is up to 99:1.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::71b52c47c252af2c5c2d4ab7e10a85da https://doi.org/10.1016/j.molcata.2005.01.019 Zobrazit plný text záznamu Full Text from ScienceDirect