The rates of bimolecular thermal reactions taking into account local medium fluctuations

Autor:	Yu. A. Chaikina
Rok vydání:	2010
Předmět:	Reaction rate Chemical kinetics Equation of state Reaction rate constant Volume (thermodynamics) Chemistry Thermodynamics Rate equation Physical and Theoretical Chemistry Chemical reaction Ideal gas
Zdroj:	Russian Journal of Physical Chemistry B. 4:1061-1068
ISSN:	1990-7923 1990-7931
Popis:	The contribution of local medium fluctuations to the rates of thermal chemical reactions was calculated for the first time. It was shown for the “ideal gas” model that the fluctuation contribution to a rate constant was proportional to the specific volume of particles and amounted to 1–10% already at densities of about 20 atmosphere densities. For this reason, chemical kinetics calculations of reaction rates should be performed taking into account local medium fluctuations before taking into account specific volume in the equation of state.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::71a8f0fbd1a08fd2cc3475fe55eabd85 https://doi.org/10.1134/s1990793110070031 Zobrazit plný text záznamu Full text from SpringerLink