Modeling and Experimental Evaluation of Thermodynamic Properties for Binary Mixtures of Dialkylcarbonate and Alkanes Using a Parametric Model

Autor:	Fernando Espiau, Juan Ortega, José Tojo, Remko Vreekamp
Rok vydání:	2007
Předmět:	Set (abstract data type) Work (thermodynamics) UNIQUAC Chemistry General Chemical Engineering Parametric model Non-random two-liquid model Thermodynamics Isobaric process Binary number General Chemistry Function (mathematics) Industrial and Manufacturing Engineering
Zdroj:	Industrial & Engineering Chemistry Research. 46:7353-7366
ISSN:	1520-5045 0888-5885
DOI:	10.1021/ie0707366
Popis:	This work shows the utility of a parametric model, as a function of concentration and temperature, to correlate isobaric vapor−liquid equilibrium data and other themodynamic properties of solutions. With the model proposed here, a procedure can be designed to correlate properties and estimate parameters by successive steps in the order (x, ) → (x, hE) → (x, gE), applied here to a set of binary systems for which experimental data already exist for these properties. Some of the steps can be omitted if the values for some of these properties are not available. The practical application is carried out on a set of binary systems of (dialkylcarbonate + alkane) for which data have been found for the three quantities. However, new experimental values of hE and gE, obtained isobarically, are also provided for the systems considered necessary to verify the model. The results of this application show a good correlation for these quantities, improving on the results of previous models of NRTL and UNIQUAC.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::719764e4accaa6b6ae81fbcccaab9ba7 https://doi.org/10.1021/ie0707366 Zobrazit plný text záznamu