Actinide Metallocene Hydride Chemistry: C–H Activation in Tetramethylcyclopentadienyl Ligands to Form [μ-η5-C5Me3H(CH2)-κC]2– Tuck-over Ligands in a Tetrathorium Octahydride Complex

Autor:	Joseph W. Ziller, Daniel J. Grant, Justin R. Walensky, Nathan A. Siladke, Michael K. Takase, William J. Evans, Laura Gagliardi, Christopher L. Webster
Rok vydání:	2013
Předmět:	Chemistry Hydride Organic Chemistry Actinide Medicinal chemistry Inorganic Chemistry Metal chemistry.chemical_compound Hydrogenolysis visual_art visual_art.visual_art_medium Organic chemistry Reactivity (chemistry) Physical and Theoretical Chemistry Metallocene
Zdroj:	Organometallics. 32:6522-6531
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om4008482
Popis:	Hydrogenolysis of the dimethyl actinide metal- locenes (C5Me4SiMe3)2UMe2 and (C5Me4H)2AnMe2 (An = Th, U) was examined for comparison with the hydrogenolysis of (C5Me5)2AnMe2 that forms the hydrides ((C5Me5)2ThH2)2, ((C5Me5)2UH2)2, and ((C5Me5)2UH)2. Parallel reactivity is not found with the (C5Me4SiMe3) � and (C5Me4H) �
Databáze:	OpenAIRE
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