The distance dependence of intramolecular electron-transfer rates: importance of the nuclear factor

Autor:	Norman Sutin, S. S. Isied, James F. Wishart, Carol Creutz, Asbed Vassilian, Harold A. Schwarz
Rok vydání:	1988
Předmět:	Electron transfer Colloid and Surface Chemistry Reaction rate constant Chemical reaction kinetics Chemistry Intramolecular force Inorganic chemistry General Chemistry Activation energy Atomic physics Biochemistry Catalysis
Zdroj:	Journal of the American Chemical Society. 110:635-637
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja00210a074
Popis:	The conventional assumption that the distance dependence of the rate constant depends only on the electronic factor is questioned. It is shown for polyproline systems that the nuclear factor is larger than the electronic factor. It is shown further, that relative importance of nuclear and electronic factors must be considered when determining the distance dependence of electron transfer rates.
Databáze:	OpenAIRE
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