| Popis: |
The solubility of aluminum for two Andisol profiles formed on pyroclastic materials and basaltic rocks from Jeju Island, Korea was investigated. It is found that high organic carbon content and ratios in the A horizons, suggesting the substantial amounts of reactive Al are associated with organic matter, whereas the low organic carbon content and the ratios in the Bo horizons indicate that a major part of the reactive Al should be bound inorganically. The differential FT-IR spectra following acid-oxalate dissolution and heating up to 150 and , and transmission electron microscope (TEM) observation confirm that imogolite is in the Bo horizon. Our results of equilibration experiments demonstrate that the Al solubility in the Bo horizon for Andisols can be clarified by the congruent dissolution model for imogolite-type material (ITM), rather than by the simultaneous equilibrium with both ITM and Al hydroxy-interlayered aluminosilicate. With results from dialysis and aging procedures, it is noted that the formation of a proto imogolite sol showing its transformation to imogolite, which supports the congruent dissolution of ITM primarily controlling the Al solubility of Andisols in Jeju Island, Korea. |
