Experimental study and thermodynamic assessment of the Zn-Fe-Ni system

Autor:	Nai-Yong Tang, Jim M. Toguri, Xuping Su
Rok vydání:	2001
Předmět:	chemistry.chemical_compound Chemistry Ternary compound General Chemical Engineering Homogeneity (physics) Thermodynamics General Chemistry Ternary operation Computer Science Applications
Zdroj:	Calphad. 25:267-277
ISSN:	0364-5916
DOI:	10.1016/s0364-5916(01)00048-7
Popis:	The Zn-rich corner of the Zn-Fe-Ni system was experimentally determined. It was found that the T phase, which was believed previously to be an extension of the binary Γ 1 phase in the Zn-Fe system, is a true ternary compound. The composition range of this phase has been determined in this study. Based on the results of the assessments of the Zn-Fe and Zn-Ni systems carried out by the authors and using information on the Fe-Ni system available in the open literature, a preliminary assessment of the Zn-Fe-Ni system was carried out. A two-sublattice model (Fe,Ni,Zn)Zn 5 was used to describe the ternary T phase. The calculated phase boundaries in the Zn-rich corner are in good agreement with experimental results. However, reproduction of the complex homogeneity range of the ternary T phase has proven challenging.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::716358878886bfbc1aca551f2b17cf91 https://doi.org/10.1016/s0364-5916(01)00048-7 Zobrazit plný text záznamu Full Text from ScienceDirect