Synthesis and self-assembly of thiol-modified tellurophenes

Autor:	Jennifer Ham, Gabrielle C. Hoover, Connie Tang, Elisa I. Carrera, Dwight S. Seferos
Rok vydání:	2018
Předmět:	chemistry.chemical_classification 010405 organic chemistry Organic Chemistry General Chemistry 010402 general chemistry Photochemistry Electrochemistry 01 natural sciences Catalysis 0104 chemical sciences chemistry X-ray photoelectron spectroscopy Electrode Monolayer Thiol Self-assembly
Zdroj:	Canadian Journal of Chemistry. 96:929-933
ISSN:	1480-3291 0008-4042
DOI:	10.1139/cjc-2018-0077
Popis:	An asymmetric thiol-modified tellurophene was designed and synthesized, and the ability of the compound to form a monolayer on a gold electrode was confirmed. The surface-active tellurophene was synthesized using Cadiot–Chodkiewicz coupling followed by ring closing and thiol modification. The tellurophene compound forms a monolayer on gold surfaces from a concentrated solution within 24 h. The ability of the compound to conjugate to gold is confirmed by X-ray photoelectron spectroscopy (XPS). A surface blocking experiment was used to evaluate the extent of formation of a monolayer on a gold electrode.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::714fbd1dcd72b86ac487da4d313f3ec1 https://doi.org/10.1139/cjc-2018-0077 Zobrazit plný text záznamu Plný text ve formátu PDF