Relationship between the crystal structure, conductive and catalytic properties of perovskites Bi4Fe2V2−2O11−
| Autor: | A. I. Pylinina, Elena I. Knyazeva, I. I. Mikhalenko |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
inorganic chemicals
010405 organic chemistry Chemistry Isobutanol Inorganic chemistry Conductance chemistry.chemical_element General Chemistry Crystal structure Activation energy 010402 general chemistry 01 natural sciences 0104 chemical sciences Catalysis Bismuth Ion chemistry.chemical_compound Dehydrogenation |
| Zdroj: | Mendeleev Communications. 29:541-543 |
| ISSN: | 0959-9436 |
| DOI: | 10.1016/j.mencom.2019.09.021 |
| Popis: | The relationship between the crystal structure of bismuth vanadates Bi4Fe2xV2−2xO11−δ, where V5+ ions are partially replaced by Fe3+ cations, and their conductive properties and catalytic activities in conversions of isobutanol was established. A correlation between concentration of Fe ions, activation energy of dehydrogenation, and conductance activation energy was revealed. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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