Design, synthesis, and optical/electronic properties of a series of sphere-rod shape amphiphiles based on the C60-oligofluorene conjugates

Autor: Hui Li, Fu-Ai Teng, Zhe-wen Han, Han Lu, Zheng-ju Zhu, Wen-Bin Zhang, Zhi-jin Wu, Yi-fang Zhang, Feng-li Liu
Rok vydání: 2017
Předmět:
Zdroj: Chinese Journal of Polymer Science. 35:503-514
ISSN: 1439-6203
0256-7679
Popis: A series of sphere-rod shape amphiphiles were designed and synthesized by connecting the rod-like oligofluorenes with different lengths (OFn) to the different positions of the spherical [60]fullerene (C60) through a rigid linkage. The conjugates were characterized by 1H-NMR, 13C-NMR, FTIR, EA and MALDI-TOF mass spectrometry. The optical and electronic properties of the conjugates were studied by UV-Vis absorption spectroscopy, fluorescence spectrometry, and cyclic voltammetry. The results from UV-Vis absorption spectroscopy and cyclic voltammetry indicated that the energy profiles of C60 and OFn remained unchanged when different lengths of OFn were attached to C60. The electron affinities of the OFn-C60 conjugates were close to that of C60, while slight electronic interaction was found between the two individual chromophores (C60 and OFn) in their ground states. The fluorescence spectra exhibited a complete fluorescence quenching in the toluene solution, suggesting an effective energy transfer from OFn to C60. It presents a systematic study on the self-assembly, structure-property relationship, and potential technical applications of the conjugates.
Databáze: OpenAIRE
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