Stable thiolate adducts of Rh2(OAc)4 – assembly of hexametallic Ni4Rh2 complexes
| Autor: | Martin Börner, Berthold Kersting, Sara Schmorl |
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| Rok vydání: | 2022 |
| Předmět: | |
| Zdroj: | Dalton Transactions. 51:59-62 |
| ISSN: | 1477-9234 1477-9226 |
| Popis: | Thiolate adducts of dirhodium(II) tetraacetate have proven difficult to prepare. We isolated a stable, paramagnetic Ni4Rh2 adduct containing Ni-based metallothiolates bound in axial positions of the Rh24+ core. The adduct formation is accompanied by a change of the magnetic exchange interaction in the dinuclear Ni2 subunits. |
| Databáze: | OpenAIRE |
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