Adiabatic and non-adiabatic corrections to properties of the hydrogen molecular cation and its isotopomers: dissociation energies and bond lengths

Autor:	Loredana Valenzano, R. E. Moss
Rok vydání:	2002
Předmět:	Hydrogen Biophysics chemistry.chemical_element Condensed Matter Physics Dissociation (chemistry) Isotopomers Electronic states Bond length chemistry Physical and Theoretical Chemistry Atomic physics Adiabatic process Molecular Biology Scaling
Zdroj:	Molecular Physics. 100:649-654
ISSN:	1362-3028 0026-8976
Popis:	A study is presented of adiabatic and non-adiabatic corrections to the dissociation energies and bond lengths of H-2(+), D-2(+) and HD+ in vibration-rotation levels of their ground electronic states, with particular attention to isotopic scaling. In previous work (Moss, R. E., 1999, Molec. Phys., 97, 1) on rotationless levels, an anomalous non-adiabatic correction to the bond length was found for v = 20, N = 0 of HD+. Other levels close to dissociation are identified that display anomalous non-adiabatic corrections to the dissociation energies and to the bond lengths. The source of these anomalies is discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::710ca2875b789f3556b27336bb39dbd4 https://doi.org/10.1080/00268970110103156 Zobrazit plný text záznamu