Synthesis of tetraazatetracenes and -pentacenes: role of the substituents for their stability

Autor:	Michaela Märken, Benjamin D. Lindner, Anthony L. Appleton, Frank Rominger, Uwe H. F. Bunz
Rok vydání:	2014
Předmět:	Organic electronics Chemistry General Chemical Engineering Organic chemistry General Chemistry
Zdroj:	Pure and Applied Chemistry. 86:483-488
ISSN:	1365-3075 0033-4545
DOI:	10.1515/pac-2013-1211
Popis:	We report the synthesis of a series of novel tetraazaacene derivatives and compare their stability with respect to size, oxidation potential and position of the TIPS-ethynyl groups. The latter has the most pronounced effects on the stability. In case of azatetracenes where TIPS-alkynes are either attached laterally or in the peri-positions, the former ones dimerized while the latter are stable. Attempts to expand this concept to the corresponding tetrakis-peri-substituted heptacenes led to the isolation of the dimerized butterfly product.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7103d9244035e0f78891d06f7681d672 https://doi.org/10.1515/pac-2013-1211 Zobrazit plný text záznamu Plný text ve formátu PDF