Copper-Containing Nanosystems Based on Macromolecular Hydrophilic Stabilizers
Autor: | L. N. Borovikova, Yu. I. Zolotova, S. V. Valueva, Olga V. Nazarova, M. E. Vylegzhanina, E. F. Panarin |
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Rok vydání: | 2019 |
Předmět: |
Aqueous solution
010405 organic chemistry Reducing agent Oxide chemistry.chemical_element Nanoparticle General Chemistry 010402 general chemistry Methacrylate 01 natural sciences Copper 0104 chemical sciences chemistry.chemical_compound chemistry Chemical engineering Copolymer Stabilizer (chemistry) |
Zdroj: | Doklady Chemistry. 489:264-266 |
ISSN: | 1608-3113 0012-5008 |
DOI: | 10.1134/s0012500819110065 |
Popis: | An original method for the synthesis of copper-containing nanosystems for biomedical applications using hydrazine hydrate as a reducing agent was developed. The process involves intermediate formation of the [Cu(NH3)4]2+ complex ion, which ensures the formation of Cu0 nanoparticles without oxide impurity. The 2-deoxy-2-methacrylamido-D-glucose copolymer with 2-(dimethylamino)ethyl methacrylate or bovine serum albumin was used as a macromolecular hydrophilic stabilizer. The spectral and structure-morphological characteristics of the nanosystems were studied. This stabilization resulted in an almost unimodal distribution of zerovalent copper nanoparticles in aqueous solutions due to their rather good shielding by macromolecules. |
Databáze: | OpenAIRE |
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