The reactions of organophosphorus inhibitors with hydroperoxide groups and peroxide radicals of polyethylene

Autor:	D. G. Pobedimskii, Sh.A. Nasybullin, P.A. Kirpichnikov, Ye.T. Denisov, V.A. Kurbatov
Rok vydání:	1976
Předmět:	chemistry.chemical_compound chemistry Radical Phase (matter) General Engineering Molecule Polyethylene Photochemistry Peroxide
Zdroj:	Polymer Science U.S.S.R.. 18:3024-3031
ISSN:	0032-3950
Popis:	By reacting with peroxide radicals phosphates retard initiation of oxidation of PE, both in the solid phase and in the melt. The efficiency of three phosphites has been determined quantitatively and it is shown that the inhibiting efficiency of phosphates increases when screening phenoxyl groups are introduced into the molecule. Phosphites rapidly destropy hydroperoxide groups in solid PE without formation of radicals.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::70f7dee6a85a3165e6a563f2a0be68cc https://doi.org/10.1016/0032-3950(76)90412-3 Zobrazit plný text záznamu