Gas-phase structures of binary cluster ions of 1,4-dioxane and water
Autor: | Yasuhiro Yamada, Kentaro Hori, Hikari Kanno |
---|---|
Rok vydání: | 2004 |
Předmět: |
Excimer laser
Chemistry medicine.medical_treatment Analytical chemistry 1 4-Dioxane Condensed Matter Physics Mass spectrometry Ion chemistry.chemical_compound Ionization medicine Cluster (physics) Density functional theory Physical and Theoretical Chemistry Time-of-flight mass spectrometry Instrumentation Spectroscopy |
Zdroj: | International Journal of Mass Spectrometry. 231:77-81 |
ISSN: | 1387-3806 |
DOI: | 10.1016/j.ijms.2003.10.002 |
Popis: | 1,4-Dioxane–water binary cluster ions are produced by supersonic expansion in gas phase. Ionization using an ArF excimer laser for time-of-flight mass spectroscopy reveals significant magic numbers at [(C4H8O2)m(H2O)n]H+, (m,n)=(3,1), (4,2), (5,3), and (6,4). The structures of the stable binary cluster ions are discussed based on density functional theory. |
Databáze: | OpenAIRE |
Externí odkaz: |