Gas-phase structures of binary cluster ions of 1,4-dioxane and water

Autor: Yasuhiro Yamada, Kentaro Hori, Hikari Kanno
Rok vydání: 2004
Předmět:
Zdroj: International Journal of Mass Spectrometry. 231:77-81
ISSN: 1387-3806
DOI: 10.1016/j.ijms.2003.10.002
Popis: 1,4-Dioxane–water binary cluster ions are produced by supersonic expansion in gas phase. Ionization using an ArF excimer laser for time-of-flight mass spectroscopy reveals significant magic numbers at [(C4H8O2)m(H2O)n]H+, (m,n)=(3,1), (4,2), (5,3), and (6,4). The structures of the stable binary cluster ions are discussed based on density functional theory.
Databáze: OpenAIRE