Synthesis, Characterization, and AC Impedance Properties of a Novel Ion-Conducting Polymer

Autor:	Frank Hipler, Rolf D. Neuser, Sven Schäfer, Tatjana Langkau, Rudolf Pietschnig, Julia Hambrock
Rok vydání:	2003
Předmět:	Conductive polymer Polymers and Plastics Proton Chemistry Bode plot Organic Chemistry Analytical chemistry Conductivity Capacitance Ion Polymer chemistry Materials Chemistry Equivalent circuit Electrical impedance
Zdroj:	Macromolecular Rapid Communications. 24:303-306
ISSN:	1022-1336
Popis:	This paper describes the preparation and characterization of a novel ion-conducting polymeric material (2). The backbone consists of alternating alkenylidene and sulfanylidene units with adjacent hydroxy groups. Fitting of the experimental impedance data of 2 in a Bode plot reveals a conductivity of 6.6 × 10−2 S · cm−1 and a capacitance of 2.2 × 10−5 F at room temperature. The deuterated derivative of 2 shows significantly lower conductivity, suggesting that the conductivity of 2 can be attributed to proton migration. Bode plot of fresh 2; experimental vs simulated; equivalent circuit (R(RQ)).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::70eac35f6b831b9d9ad81bf647d2cb57 https://doi.org/10.1002/marc.200390046 Zobrazit plný text záznamu Plný text