Synthesis of Spiranes by Thiol-Mediated Acyl Radical Cyclization

Autor:	Chih-Hao Chen, Chi-Wei Hsu, Day‐Shin Hsu
Rok vydání:	2015
Předmět:	chemistry.chemical_classification 010405 organic chemistry Chemistry Organic Chemistry 010402 general chemistry 01 natural sciences Radical cyclization Toluene 0104 chemical sciences Acylation chemistry.chemical_compound Thiol Organic chemistry Physical and Theoretical Chemistry
Zdroj:	European Journal of Organic Chemistry. 2016:589-598
ISSN:	1434-193X
DOI:	10.1002/ejoc.201501305
Popis:	A general and efficient method for the preparation of spiro compounds is described. Various enone-aldehydes were exposed to t-dodecanethiol and AIBN at 75 °C in toluene to afford spirocyclic 1,4-diketones in moderate to good yields.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::70e765621e433b0b92e062f908a3af4c https://doi.org/10.1002/ejoc.201501305 Zobrazit plný text záznamu