Regioselectivity of the addition of •CCl3 and •But radicals to (η2-C70)[Os(CO)(PPh3)2(CNBut)] n (n = 1, 2): an ESR study

Autor:	Yu. N. Novikov, E. V. Martynova, R. G. Gasanov, M. V. Tsikalova, I. V. Stankevich
Rok vydání:	2010
Předmět:	Chemistry Radical Regioselectivity General Chemistry Photochemistry Medicinal chemistry Adduct Metal Delocalized electron Unpaired electron visual_art Electronic effect visual_art.visual_art_medium Spectroscopy
Zdroj:	Russian Chemical Bulletin. 59:1707-1712
ISSN:	1573-9171 1066-5285
DOI:	10.1007/s11172-010-0300-3
Popis:	The addition of •CCl3 and •But radicals to (η2-C70)Os(CO)(PPh3)2(CNBut) (1) and (η2-C70)[Os(CO)(PPh3)2(CNBut)]2 (3) was studied by ESR spectroscopy. The metal fragment in complex 1 does not influence the regioselectivity of the addition of the radicals to it. The stability of the spin adducts formed upon addition of free radicals to complexes 1 and 3 is mainly governed by delocalization of the unpaired electron over three hexagonal rings.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::70e0a743eaad640622f7ea4b32f790b5 https://doi.org/10.1007/s11172-010-0300-3 Zobrazit plný text záznamu Full text from SpringerLink