Piceanonols A, and B, triterpenoids bearing a novel skeletal system isolated from the bark of Picea jezoensis var. hondoensis

Autor: Yasuko In, Reiko Tanaka, Tsuyoshi Kumagai, Hoyoku Nishino, Shunyo Matsunaga, Toshimasa Ishida
Rok vydání: 1999
Předmět:
Zdroj: Tetrahedron Letters. 40:6415-6418
ISSN: 0040-4039
Popis: A CHCl 3 extract of the stem bark of Picea jezoensis var. hondoensis (Pinaceae) afforded two triterpenoids named piceanonols A and B with a novel 14(13 → 12) abeo -12α H -serratane skeleton. Extensive NMR studies, MS spectral analyses and X-ray crystallographics established their structures as 3β-methoxy-14β,21β-dihydroxy-14(13 → 12) abeo -12α H -serratan-13-one and 21α-methoxy-14β-hydroxy-14(13 → 12) abeo -12α H -serratane-3,13-dione.
Databáze: OpenAIRE