The structure of dichlorodimethylbis(pyrazole-N2)tin(IV)
| Autor: | Valerio Peruzzo, Giovanni Valle, Renato Ettorre, Gualtiero Plazzogna |
|---|---|
| Rok vydání: | 1987 |
| Předmět: |
Hydrogen bond
Stereochemistry Organic Chemistry chemistry.chemical_element Crystal structure Pyrazole Biochemistry Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry X-ray crystallography Materials Chemistry Molecule Physical and Theoretical Chemistry Tin Single crystal Monoclinic crystal system |
| Zdroj: | Journal of Organometallic Chemistry. 326:169-172 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/0022-328x(87)80154-7 |
| Popis: | The structure of the complex Sn(CH3)2Cl2·2C3H4N2 has been determined by single crystal X-ray diffraction methods. The compound crystallizes in the monoclinic system, space Group C2/c (no. 15), with unit cell dimensions a 14.010(4), b 7.906(3), c 13.617(4) A, β 114.7(3)°, and Z = 4. The configuration about the tin atom is all-trans-octahedral. The pyrazole ligands, coordinated through the imino nitrogen atom, are intramolecularly and intermolecularly hydrogen bonded to the chloride ligands, the N(1)H … Cl distances being 3.480 and 3.297 A, respectively. Structural features of the complex are compared with those of other complexes of N-bonded heterocyclic ligands of the type Sn(CH3)2Cl2·2L. |
| Databáze: | OpenAIRE |
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