The structural characterization of the novel ribbon sheet, [Cu2Cl2(pyz)]n (pyz = pyrazine)

Autor:	Kumagai Hitoshi, Kitagawa Susumu, Katada Motomi, Iwabuchi Shinichiro, Kawata Satoshi
Rok vydání:	1998
Předmět:	Pyrazine Chemistry chemistry.chemical_element Crystal structure Triclinic crystal system Copper Ion Inorganic Chemistry chemistry.chemical_compound Crystallography Zigzag Ribbon Materials Chemistry Molecule Physical and Theoretical Chemistry
Zdroj:	Inorganica Chimica Acta. 267:143-145
ISSN:	0020-1693
DOI:	10.1016/s0020-1693(97)05558-8
Popis:	The new copper(I) sheet compound [Cu2Cl2(pyz)]n (pyz = pyrazine) (1) has been synthesized and characterized. 1 crystallizes in the triclinic, space group P 1 with a = 6.885(2) A , b = 7.5719(6) A , c = 3.752(1) A , α = 98.84(1)°, β = 92.27(2)°, γ = 106.55(2)°, U = 184.55(7) A 3 , and Z = 1 . Crystal structure consists of one-dimensional CuCln ladders and stacked pyz columns. Infinite, zigzag ribbons are formed by Cu(I) ions and chlorides. The ladders extend along the c-direction, and are linked by pyz molecules which coordinate to adjacent copper atoms, forming a two-dimensional sheet. The pyz molecules are stacked in the sheet and make a column along the c-axis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::70bb45f7ab3ef6920d2259e82198e632 https://doi.org/10.1016/s0020-1693(97)05558-8 Zobrazit plný text záznamu Full Text from ScienceDirect