Recent Developments in the Nitroxide-Catalyzed Oxidation of Amines: Preparation of Imines and Nitriles

Autor:	Kyle M. Lambert, James M. Bobbitt, Ashley L. Bartelson, William F. Bailey
Rok vydání:	2016
Předmět:	Reaction mechanism Nitroxide mediated radical polymerization Allylic rearrangement Nitrile 010405 organic chemistry Organic Chemistry Imine 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound chemistry Organic chemistry Physical and Theoretical Chemistry
Zdroj:	ChemCatChem. 8:3421-3430
ISSN:	1867-3880
Popis:	This Concept highlights the discovery and developments in the oxidations of amines catalyzed by TEMPO (2,2,6,6-tetramethylpiperidinyl-N-oxyl) and related catalytic systems. The most important feature of these systems is that, with slight modifications in the reaction media, amines are selectively oxidized to either an imine or nitrile. Progress made toward the oxidation of various benzylic, allylic, and aliphatic amines and possible reaction mechanism pathways are discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7097ecee371645f50c2aa7be55c51171 https://doi.org/10.1002/cctc.201600858 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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