First molecular conductors of BPDT-TTF with metallacarborane anions: (BPDT-TTF)[3,3′-Сr(1,2-C2B9H11)2] and (BPDT-TTF)[3,3′-Сo(1,2-C2B9H11)2] – Synthesis, structure, properties

Autor:	Olga N. Kazheva, Andrey V. Kravchenko, Igor B. Sivaev, Gennady V. Shilov, Ekaterina A. Komissarova, Elena V. Shklyaeva, Oleg A. Dyachenko, Irina D. Kosenko, Denis M. Chudak, Vladimir A. Starodub, Lev I. Buravov, I. A. Shilova, Vladimir I. Bregadze, G. G. Abashev
Rok vydání:	2018
Předmět:	010405 organic chemistry Chemistry business.industry Organic Chemistry Crystal structure 010402 general chemistry 01 natural sciences Biochemistry 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound Crystallography Semiconductor Transition metal Electrical resistivity and conductivity Materials Chemistry Physical and Theoretical Chemistry business Electrical conductor Tetrathiafulvalene
Zdroj:	Journal of Organometallic Chemistry. 867:375-380
ISSN:	0022-328X
DOI:	10.1016/j.jorganchem.2018.01.050
Popis:	The first molecular conductors based on bis(1,3-propylenedithio)tetrathiafulvalene and transition metal bis(dicarbollides) (BPDT-TTF)[3,3′-Сr(1,2-C2B9H11)2] (1) and (BPDT-TTF)[3,3′-Сo(1,2-C2B9H11)2] (2) were synthesized and their crystal structures were determined by X-ray analysis. The electric conductivity measurements revealed that these compounds are semiconductors at room temperature.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7096ab075f9918b1e4d13ea3a77ab2e4 https://doi.org/10.1016/j.jorganchem.2018.01.050 Zobrazit plný text záznamu Full Text from ScienceDirect