Effect of a three-component initiation system ferrocene-zirconocene dichloride-benzoyl peroxide on the free-radical polymerization of methyl methacrylate
| Autor: | V. A. Kraikin, Regina M. Islamova, Yu. I. Puzin, L. V. Spirikhin, Yu. B. Monakov, G. R. Sadykova |
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| Rok vydání: | 2008 |
| Předmět: |
Polymers and Plastics
Bulk polymerization Radical polymerization Benzoyl peroxide Peroxide chemistry.chemical_compound Polymerization chemistry Polymer chemistry Materials Chemistry Ceramics and Composites Precipitation polymerization medicine Coordination polymerization Ionic polymerization medicine.drug |
| Zdroj: | Polymer Science Series B. 50:128-133 |
| ISSN: | 1555-6123 1560-0904 |
| DOI: | 10.1134/s1560090408050060 |
| Popis: | The free-radical polymerization of methyl methacrylate initiated by the three-component system ferrocene-zirconocene dichloride-benzoyl peroxide has been studied. The kinetic features of the process, the interaction between components of the initiation system, and the molecular characteristics of the polymers have been investigated. In the case of the three-component initiation system, the content of syndiotactic fragments grows and the thermal stability of the polymers is improved compared to the products of polymerization carried out in the presence of solely a peroxide initiator. |
| Databáze: | OpenAIRE |
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