The mechanism of the photo-induced decarboxylatton of pyruvic acid in solution

Autor:	R.Stephen Davidson, Dean Goodwin, Ph. Fornier de Violet
Rok vydání:	1981
Předmět:	chemistry.chemical_compound Electron transfer chemistry Decarboxylation Excited state General Physics and Astronomy Pyruvic acid Physical and Theoretical Chemistry Triplet state Benzene Acetonitrile Photochemistry Naphthalene
Zdroj:	Chemical Physics Letters. 78:471-474
ISSN:	0009-2614
DOI:	10.1016/0009-2614(81)85239-6
Popis:	It is proposed that photo-induced decarboxylation of pyruvic acid occurs via electron transfer from an excited to a ground-state molecule. Quantum yields of triplet production at 295 K in deoxygenated benzene, acetonitrile and water are 0.65, 0.88 and 0.22. The triplet state of naphthalene is quenched by pyruvic acid and it is suggested that this occurs via electron transfer.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7059fd6c1411ff73b641608447daa8e7 https://doi.org/10.1016/0009-2614(81)85239-6 Zobrazit plný text záznamu