Normal phase thin layer chromatography for aromatic derivatives of 3-chloro-1,4-naphtochinone

Autor: S. V. Kolobych, O. Ya. Smirnova, I. P. Poliuzhyn, Yo. Yo. Yatchyshyn
Rok vydání: 2021
Předmět:
Zdroj: Chemistry, Technology and Application of Substances. 4:33-43
ISSN: 2664-1569
2617-7307
DOI: 10.23939/ctas2021.01.033
Popis: The chromatographic characteristics were investigated for eight aromatic derivatives of 3-chloro-1,4-naphthoquinone under conditions of normal-phase thin-layer chromatography for benzene-based binary mobile phase and such polar solvents as chloroform, acetone, acetonitrile, methanol and propan-2-ol. The slope of linear retention dependencies for the investigated compounds on the concentration of the polar component in the mobile phase satisfactorily correlates with the area occupied by the adsorbed analyte molecule in the stationary phase. The intercept in the Soczewinski equation depends on the polar component of the mobile phase.
Databáze: OpenAIRE